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Depending on concentration, transition-metal availability, oxygen tension, and enzymatic context, polyphenols can generate semiquinones, quinones, hydrogen peroxide, or glutathione-consuming intermediates that shift a system from cytoprotection toward oxidative damage ( 3 Interfacial mechanisms of phenolic functionalization on MSNs 3.1 Adsorption and confinement-dominant loading Adsorption-dominant loading is based mainly on non-covalent affinity between phenolics and the pore/surface environment

Chemical structures of lipoic acid and lipoyllysine residue The figure illustrates the chemical structures of lipoic acid in its oxidized and reduced forms, its two enantiomers ( R - and S -lipoic acid), and its covalent attachment to a lysine residue of the E2 component of the -ketoacid dehydrogenase complex (and the H protein of the glycine cleavage system), forming a lipoyllysine moiety

Funding The current research has received no funding from agencies in the public, commercial, or not-for-profit sectors