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Hence, although future kinetic studies might confirm a random mechanism for the rate-limiting first part of monothiol mechanism (iii) in vitro, GSH is probably the first and the non-glutathione disulfide the second substrate under physiological conditions in vivo (Fig

4 Examples of these proteins can be found particularly in central carbon metabolism that becomes essential in an infection under these conditions 5,6 and in DNA synthesis 7,8 and, more generally, nucleic acid metabolism

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