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The list of species and NCBI accession numbers, as well as the corresponding peptide sequences, are provided in Supplementary Tables 15 and 16

Polar metabolites identification was according to the MS/MS spectra, the retention time of commercially available standard compounds, and the accurate mass of compounds from the Human Metabolome Database (www.hmdb.ca) and MassBank of North America ( Lipids were identified based on MS/MS match by using the LipidSearch software v4.1 (Thermo Fisher Scientific, CA, USA)