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These toothpastes use several mechanisms: Mild abrasives (like hydrated silica or calcium carbonate): Physically polish away surface stains Chemical agents (hydrogen peroxide or carbamide peroxide): Help lighten stains Enzymes : Break down protein-based stains Optical brighteners : Create an immediate illusion of whiter teeth by reflecting light I regularly advise my patients about whitening options, noting the significant differences between UK and US regulations